\(n_{AlCl_3}=0,1 \times 1 = 0,1 (mol)\)
\(n_{Al_2O_3}= \dfrac {2,55}{102}=0,025(mol)\)
Có hai trường hợp:
a. NaOH thiếu
\(AlCl_3 + 3NaOH \rightarrow Al(OH)_3\downarrow + 3NaCl\) (1)
3 x 0,05mol 0,05mol
\(2Al(OH)_3 \xrightarrow[]{t^o} Al_2O_3 + 3H_2O\) (2)
0,05mol 0,025mol
Vậy, \(C_{M(NaOH)}= \dfrac {0,15}{0,2}=0,75(M)\)
b. NaOH dư một phần:
\(AlCl_3 + 3NaOH \rightarrow Al(OH)_3 +3NaCl\) (1)
o,1mol 0,3mol 0,1mol
\(Al(OH)_3 + NaOH \rightarrow NaAlO_2 + 2H_2O\) (2)
0,05mol 0,05mol
\(2Al(OH)_3 \xrightarrow[]{t^o} Al_2O_3 + 3H_2O\) (3)
0,05mol 0,025mol
\(\Rightarrow n_{NaOH}=0,3+0,05=0,35(mol)\)
\(C_{M(NaOH)} \dfrac {0,35}{0,2}=1,75(M)\)
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