A. 75 gam.
B. 125 gam.
C. 150 gam.
D. 225 gam.
A
Đáp án A
Phương trình phản ứng:
\(\begin{align} & \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{O}_{2}}+Ca{{(OH)}_{2}}\to CaC{{O}_{3}}+{{H}_{2}}O\,\,\,\,\,\,\,\left( 1 \right) \\ & mol\,\,\,\,\,\,\,0,55\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\leftarrow 0,55 \\ \end{align}\) \(\begin{align} & \,\,\,\,\,\,\,\,\,\,\,\,\,\,2C{{O}_{2}}+Ca{{(OH)}_{2}}\to Ca{{(HC{{O}_{3}})}_{2}}\,\,\,\,\,\,\left( 2 \right) \\ & mol\,\,\,\,\,\,\,0,2\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\leftarrow 0,1 \\ \end{align}\) \(\begin{align} & \,\,\,\,\,\,\,\,\,\,\,\,Ca{{(HC{{O}_{3}})}_{2}}\xrightarrow{{{t}^{o}}}CaC{{O}_{3}}+C{{O}_{2}}+{{H}_{2}}O\,\,\,\,\,\,\left( 3 \right) \\ & mol\,\,\,\,\,\,\,\,\,\,0,1\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\leftarrow \,\,\,\,\,\,\,\,\,\,0,1 \\ \end{align}\) \(\begin{align} & \,\,\,\,\,\,\,\,\,\,\,\,{{C}_{6}}{{H}_{12}}{{O}_{6}}\xrightarrow{le\hat{a}n\,\,men\,\,r\ddot{o}\hat{o}\ddot{i}u}2{{C}_{2}}{{H}_{5}}OH+2C{{O}_{2}}\,\,\,\,\,\,\left( 4 \right) \\ & mol\,\,\,\,\,\,0,375\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\leftarrow \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,0,75 \\ \end{align}\) \(\begin{align} & \,\,\,\,\,\,\,\,\,\,\,\,{{({{C}_{6}}{{H}_{10}}{{O}_{5}})}_{n}}+n{{H}_{2}}O\xrightarrow{xt}n{{C}_{6}}{{H}_{12}}{{O}_{6}}\,\,\,\left( 5 \right) \\ & mol\,\,\,\,\,\,\,\,\frac{0,375}{n}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\leftarrow \,\,\,\,\,\,\,\,\,\,\,0,375 \\ \end{align}\)
Theo giả thiết ta thấy khi CO2 phản ứng với dung dịch Ca(OH)2 thì tạo ra cả hai loại muối là CaCO3 và Ca(HCO3)2. Từ các phản ứng (1), (2), (3), (4), (5) suy ra:
\({{n}_{{{({{C}_{6}}{{H}_{10}}{{O}_{5}})}_{n}}}}=\frac{0,375}{n}mol.\)
Vậy khối lượng tinh bột tham gia phản ứng với hiệu suất 81% là:
\({{m}_{{{C}_{6}}{{H}_{10}}{{O}_{5}}}}=\frac{162n.0,375}{n.81%}=75\,(gam).\)
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